"(＊๑ᵕ̣̣̣̣̣̣︹ᵕ̣̣̣̣̣̣)" is a Japanese-style emoticon typically used to convey shyness, embarrassment, or cuteness.
"She broke with me" emote is not a commonly recognized emoticon. It could potentially be a custom emoticon created by an individual to express their emotions related to a breakup.